有機-無機複合混成材料於溶膠-凝膠反應之應用

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doi:10.6342/NTU201700047

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有机-无机复合混成材料於溶胶-凝胶反应之应用

Application of organic - inorganic hybrid composites material via sol - gel reaction

刘正伟 , 博士　　导师：谢国煌　　

繁体中文 DOI： 10.6342/NTU201700047

溶胶-凝胶；混成材料； sol-gel ； hybrid

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摘要 │ 参考文献 (106) │ 国际计量

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In this study, to development a series of novel materials that can protect the surface of the rock, polycarbonate and polyethylene terephthalate. In part I, silane-modified resin (epoxy-silane resin, ES) was synthesized by 3-Aminopropyl trimethoxy silane (APS), 3-Glycidyloxypropyl trimethoxy silane (GPS), diglycidyl ether of bisphenol A (DGEBA) and polytetramethylene ether glycol 2000 (PTMEG 2000) via polycondensation reaction. The Si-O-Si bond was formed between the resin and the rock via sol-gel reaction in order to strength the sandstone surface’s mechanical properties and weatherability. Furthermore, the nano silicate platelets (NSP) were also involved into the system for the purpose of introducing extra covalent bonding of the rock-based nanocomposites. Point load and Slake-durability tests were carried out to illustrate the effects of silane-introduction to the strength and weathering resistance of the rock-based nanocomposite.In part II, the multi-functional methacrylates are prepared through polycondensation by isophorone diisocynante (IPDI), pentaerythritol triacrylate (PETA) reacting with epoxy acrylate, 2,2-bis[4-(20-hydroxy-30-methacryloyloxypropoxy)phenyl]propane (Bis-GMA), the series of  urethane epoxy acrylate resins are successfully synthesized. The urethane epoxy acrylate oligomer’s structure is characterized by Fourier transform infrared spectroscopy (FT-IR). In order to enhance the hardness of the resins, the colloidal silica is successfully reacted with 3-(trimethoxy silyl)propyl methacrylate (MSMA). The characteristics of the colloidal silica/MSMA are measured by means of dynamic light scattering (DLS). The acrylate functional groups are chemically bonded to the surface of the silica spheres, enhancing the compatibility of the organic/inorganic interface; the highest hardness can reach 7H, and the adhesion of the PC & PET reaches 5B. The thermal properties of the cured coating are investigated by means of thermal gravimetric analysis (TGA), with the decomposition temperature (Td) reaching up to 440 ℃.

参考文献 ( 106 ) 〈TOP〉

1. H. Kilambi, J.W. Stansbury, C.N. Bowman, Deconvoluting the Impact of Intermolecular and Intramolecular Interactions on the Polymerization Kinetics of Ultrarapid Mono(meth)acrylates, Macromolecules, 2007, 40, 47.
连结：
2. F.H. Huang, C.C. Chang, T.Y. Oyang, C.C. Chen, L.P. Cheng, Preparation of almost dispersant-free colloidal silica with superb dispersiblility in organic solvents and monomers, J Nanopart Research ,2011, 13 , 3885–3897.
连结：
3. C.C. Chang, T.Y. Oyang, F.H. Hwang, C.C. Chen, L.P. Cheng, Preparation of polymer/silica hybrid hard coatings with enhanced hydrophobicity on plasticsubstrates, Journal of Non-Crystalline Solids, 2012, 358, 72–76.
连结：
4. B.R. Flachsbart, K. Wong, J.M. Iannacone, E.N. Abante, R.L. Vlach, P.A. Rauchfuss, P.W. Bohn, .V. Sweedler, M.A. Shannon, Design and fabrication of a multilayered polymer microfluidic chip with nanofluidic interconnects via adhesive contact printing, Lab Chip, 2006, 6, 667–674.
连结：
5. R. Fateh, R. Dillert, D. Bahnemann, Preparation and Characterization of Transparent Hydrophilic Photocatalytic TiO2/SiO2 Thin Films on Polycarbonate, Langmuir 2013, 29, 3730−3739.
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使用DOI作为永久连结

引用含有DOI的文献

DOI可强化引用精确性、增强学术圈连结，并给予使用者跨平台的良好使用经验，目前在全世界已有超过五千万个对象申请DOI。 如想对DOI的使用与概念有进一步了解，请参考 （ ） 。

DOI可强化引用精确性、增强学术圈连结，并给予使用者跨平台的良好使用经验，目前在全世界已有超过五千万个对象申请DOI。如想对DOI的使用与概念有进一步了解，请参考（）。