以溶液製程製作高效率鈣鈦礦太陽能電池及結合透明電極之研究

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doi:10.6342/NTU201602790

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以溶液制程制作高效率钙钛矿太阳能电池及结合透明电极之研究

Efficient Solution Process Perovskite Solar Cell and Transparent electrode

程薇心 , 硕士　　导师：吴志毅　　

繁体中文 DOI： 10.6342/NTU201602790

钙钛矿太阳能电池；湿式制程；新型六苯并蒄分子；石墨烯；透明电极； Perovskite solar cells ； Solution process ； HBC-6ImBr (Hexa-peri-hexabenzocoronene-6ImBr) ； Graphene ； Transparent electrode

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摘要 │ 参考文献 (41) │ 国际计量

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In the first part of this thesis, the optimized performance of Perovskite solar cells in conventional structure using drop-casting solution process has been achieved. Devices performance were sequentially improved by several testing, including thickness and the layer number of titanium dioxide (TiO2) which is used as electron transporting layer (ETL), annealing time, annealing temperature and thickness of Perovskite which is used as light absorption layer, thickness of hole transport layer (HTL) of N2,N2,N2′,N2′,N7,N7,N7′,N7′-octakis(4-methoxyphenyl)-9,9′-spirobi [9H-fluorene] -2,2′,7,7′-tetramine (Spiro-MeOTAD) and anode(Au) .The mechanisms behind for each part have been discussed as well. Via the measurement of Scanning electron microscopy(SEM) and X-ray diffraction(XRD),it proves that the drop-casting process is beneficial for crystallization of Perovskite. Finally the power conversion efficiency of the Perovskite solar cells in this study has achieved over 15.7%, with a filling factor (F.F) of 72%.
  In the second part, we successfully fabricate inverted perovskite solar cells using graphene as bottom anode. In order to convert graphene’s hydrophobic nature into hydrophilic, we insert a buffer material called HBC-6ImBr (Hexa-peri- hexabenzocoronene-6ImBr) between graphene and HTL. Besides, we find that cracks of graphene can be covered by stacking multilayer of graphene and effectively improve the device performance such as shunt resistance. Our best cell with tri-layer HBC-6ImBr and tri-layer graphene has reached 7.1% of power conversion efficiency and a fill factor of around 52%. At last, we try to replace Ag with sliver nano-wire (Ag-NW) to fabricate transparent devices in inverted structure with appropriate annealing temperature.

参考文献 ( 41 ) 〈TOP〉

[1] “Polythiophenes Comprising Conjugated Pendants for Polymer Solar Cells: A Review” Materials 2014, 7(4), 2411-2439
连结：
[4] “Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells.” Akihiro Kojima , Kenjiro Teshima, Yasuo Shirai and Tsutomu Miyasaka. Journal of the American Chemical Society, 131 (17).
连结：
[5] “Cesium-containing Triple Cation Perovskite Solar Cells: Improved Stability, Reproducibility and High Efficiency.” Saliba M, Matsui T, Seo J-Y, Domanski K, Correa-Baena J-P, Nazeeruddin MK, Zakeeruddin SM, Tress W, Abate A, Hagfeldt A, Grätzel M. Energy and Environmental Science 16 March 2016
连结：
[6] “Perovskite-based low-cost and high-efficiency hybrid halide solar cells.” Jiandong Fan, Baohua Jia and Min Gu Photonics. Photonics Research Vol. 2, Issue 5, pp. 111-120 (2014).
连结：
[7] “Lead Iodide Perovskite Sensitized All-Solid-State Submicron Thin Film Mesoscopic Solar Cell with Efficiency Exceeding 9%.” Hui-Seon Kim, Chang-Ryul Lee, Jeong-Hyeok Im, Ki-Beom Lee, Thomas Moehl. Scientific Reports, 2012; 2: 591.
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引用含有DOI的文献

DOI可强化引用精确性、增强学术圈连结，并给予使用者跨平台的良好使用经验，目前在全世界已有超过五千万个对象申请DOI。 如想对DOI的使用与概念有进一步了解，请参考 （ ） 。

DOI可强化引用精确性、增强学术圈连结，并给予使用者跨平台的良好使用经验，目前在全世界已有超过五千万个对象申请DOI。如想对DOI的使用与概念有进一步了解，请参考（）。