奈米碳管接枝4, 4-二異氰酸二苯甲烷/碳纖維/共聚物高分子之機械性質暨疲勞行為

江浩

山西大学，您好！

感谢采购，人社期刊库｜人社论文库，期间：2025/01/01~2025/12/31

感谢试用，科学期刊库｜科学论文库，期间：2024/10/20~2025/01/20

浏览高级检索

关闭
检索检索高级检索出版物检索
浏览期刊主题浏览核心期刊浏览期刊拼音浏览

关闭

查询符号(半角)	查询符号意义说明
空格	表示为「AND」两个查询词之交集
双引号 ( " " )	片语以双引号标示开始及结束，而且只寻找出现顺序相同的字词，例： " image process "
?	表示一个字母切截，输入两个?表两个字母，依此类推，例：输入「Appl?」，查得结果应为appl e , appl y … ( 常用于英文字查询 )
*	表示不限字母切截，由0~n. 例：输入「appl*」，查得结果应为appl e , appl es , appl y , appl ied , appl ication … ( 常用于英文字查询 )
AND、OR、NOT	布尔逻辑组合关键字，用来扩大或缩小查询范围的技巧。 (1) AND ：缩小查询范围 (2) OR ：扩大查询范围(3) NOT：排除不相关的范围

DOI 是数位物件识别码（ D igital O bject I dentifier ）的简称，
为物件在网路上的唯一识别码，可用于永久连结并引用目标物件。

使用DOI作为永久连结

每个DOI号前面加上「 http://dx.doi.org/ 」便成为永久网址。
如以DOI号为 10.5297/ser.1201.002 的文献为例，此文献的永久连结便是： http://dx.doi.org/ 10.5297/ser.1201.002 。
日后不论出版单位如何更动此文献位置，永久连结所指向的位置皆会即时更新，不再错失重要的研究。

引用含有DOI的文献

有DOI的文献在引用时皆应同时引用DOI。若使用APA、Chicago以外未规范DOI的引用格式，可引用DOI永久连结。

DOI可强化引用精确性、增强学术圈连结，并给予使用者跨平台的良好使用经验，目前在全世界已有超过五千万个对象申请DOI。如想对DOI的使用与概念有进一步了解，请参考（）。

书目管理工具

相关连结

问题回报

全文下载

奈米碳管接枝4, 4-二异氰酸二苯甲烷/碳纤维/共聚物高分子之机械性质暨疲劳行为

Investigation of Mechanical Properties and Fatigue Behavior of 4, 4’-Methylenediphenyl diisocyanate grafted Carbon Nanotubes / Copolymer / Carbon Fiber Reinforced Laminated Composite

江浩 , 硕士　　导师：蔡宏营　　

繁体中文

改质奈米碳管；环氧树脂；氧代氮代苯并还己烷；碳纤维；机械性质；疲劳行为；复合材料； Chemical modified carbon nanotubes ； Epoxy ； Benzoxazine ； Carbon fiber ； Mechanical properties ； Fatigue behavior ； Composite

0 个人觉得这篇文章赞

摘要 │ 参考文献 (60) │ 国际计量

摘要〈TOP〉

并列摘要〈TOP〉

In recent years, due to rapid growth of industrial and academic development, carbon reinforced polymer composite has been paid much attention and further applied to a wide variety of fields from industrial applications to daily necessities. This study is going to choose benzoxazine/epoxy copolymer as the matrix of composite in which carbon nanotubes is added to bridge the matrix and fiber in order to achieve the goal of improvement in mechanical properties and fatigue behavior.
　　To enhance the ability of dispersion and interfacial property of carbon nanotubes in the matrix, carbon nanotubes will be firstly treated by nitric acid, which is to increase the surface reactivity. Carbon nanotubes are then chemically modified by 4, 4’-Methylenediphenyl diisocyanate (MDI) so as to improve the compatibility among different phases of materials. In the end of this study, mechanical properties and fatigue behavior will be clearly discussed.
　　Success of chemical modification of carbon nanotubes can be proved by a series of chemical identifications such as Raman spectrum, Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), Thermogravimetric analysis (TGA) and so on. Additionally, the result of Dynamic mechanical analysis (DMA) also shows that glass transition temperature of modified carbon nanotubes based polymer composite increases by about 12 degrees and that the increasing cross-linking density significantly improves the mechanical properties compared with pure polymer matrix.
　　Last but not least, the results of static mechanical properties and dynamic fatigue behavior are investigated and revealed great improvement by adding chemical modified carbon nanotubes, which are able to keep carbon fiber laminates from delaminating so easily and effectively lengthen the fatigue life of carbon fibrous composite.

参考文献 ( 60 ) 〈TOP〉

[1] Riccardi, C. C. and Williams, R. J. J., 1986, “A kinetic scheme for an amine-epoxy reaction with simultaneous etherification,” Journal of Applied Polymer Science, 32(2), pp. 3445-3456.
连结：
[2] 王国书, 2007, “奈米碳管/高分子预浸材积层板复合材料之机械与电性质研究,” 国立清华大学动力机械工程学系硕士论文.
连结：
[4] 游俊盟,2005, “马来醯胺- 氧代氮代苯并环已烷之合成、聚合及硬化树脂研究,”私立中原大学化学工程学系硕士论文.
连结：
[5] Holly, F. W. and Cope, A. C., 1944, “Condensation Products of Aldehydes and Ketones with o-Aminobenzyl Alcohol and o-Hydroxybenzylamine,” Journal of the American Chemical Society, 66(11), pp. 1875-1879.
连结：
[6] Ning, X. and Ishida, H., 1994, “Phenolic materials via ring-opening polymerization: Synthesis and characterization of bisphenol-A based benzoxazines and their polymers,” Journal of Polymer Science Part A: Polymer Chemistry, 32(6), pp. 1121-1129.
连结：

国际计量

〈TOP〉

E-mail ：

文章公开取用时，将寄通知信至您填写的信箱地址

E-mail ：

使用DOI作为永久连结

引用含有DOI的文献

DOI可强化引用精确性、增强学术圈连结，并给予使用者跨平台的良好使用经验，目前在全世界已有超过五千万个对象申请DOI。 如想对DOI的使用与概念有进一步了解，请参考 （ ） 。

DOI可强化引用精确性、增强学术圈连结，并给予使用者跨平台的良好使用经验，目前在全世界已有超过五千万个对象申请DOI。如想对DOI的使用与概念有进一步了解，请参考（）。