三成份鎳-鈷系尖晶石氧化物於可充式 鋅空氣電池之空氣極的研究

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三成份镍-钴系尖晶石氧化物於可充式锌空气电池之空气极的研究

Ternary Spinel Nickel-Cobalt-Based Oxides for the Air Electrode of Rechargeable Zinc-Air Batteries

简佑如 , 硕士　　导师：胡启章　　

繁体中文

锌空气电池；氧气产生；氧气还原；镍钴氧化物；尖晶石氧化物； zinc air battery ； OER ； ORR ； nickel cobalt oxide ； spinel oxide

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摘要 │ 参考文献 (95) │ 国际计量

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There are two parts in this research. In the first part, partially substituted MxNi1-xCo2O4 (M = Mn, Fe, Cu, and Zn, x=0.1) spinel oxides, labeled as MNCO-01, FNCO-01, CNCO-01, and ZNCO-01, were synthesized via a facilely hydrothermal method. The effects of the metal  partially substitution in the Ni site of the spinel oxide on the morphology and electrocatalytic properties of the materials toward the ORR and OER were investigated and compared by using X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy  (TEM), inductively coupled plasma-mass spectrometer (ICP-MS),  X-ray photoelectron spectroscopy (XPS), surface area analyzer and electrochemical techniques including cyclic voltammetry (CV), linear sweep voltammetry (LSV), tafel plot, and galvanodynamic charge-discharging. As a result, the iron-substituted nickel-cobalt based oxides (FNCO-01) displayed a significant electrocatalytic activity towards both the ORR and OER in comparison with the Mn-substituted, Cu-substituted, and Zn-substituted nickel-cobalt based oxides. 
In the second part, the spinel-type ternary transition metal oxides of nickel, cobalt, and iron with the composition FexNi1-xCo2O4 (0 ≤ x ≤ 1) were prepared and tested as promising electrocatalysts for the ORR and OER in alkaline solution. The structural, morphological and electrocatalytic performances confirmed that substitution of Ni by Fe increases the electrocatalytic activity of the resulting material significantly. The highest activity was achieved for FexNi1-xCo2O4 with 0.1 ≤ x ≤ 0.3. The practicality of the catalyst were corroborated by testing in a realistic rechargeable zinc-air battery utilizing atmospheric air in ambient conditions, where FexNi1-xCo2O4 (x=0.3) demonstrated superior charge and discharge voltages and long-term cycle stability with virtually no battery voltage fading. The excellent electrochemical results presented in this study highlight the FexNi1-xCo2O4 as highly efficient and commercially viable bifunctional catalyst for rechargeable metal-air battery application.

参考文献 ( 95 ) 〈TOP〉

[2] M. Winter and R. J. Brodd, "What are batteries, fuel cells, and supercapacitors?," Chemical reviews, vol. 104, pp. 4245-4270, 2004.
连结：
[4] V. Neburchilov, H. Wang, J. J. Martin, and W. Qu, "A review on air cathodes for zinc-air fuel cells," Journal of Power Sources, vol. 195, pp. 1271-1291, 3/1/ 2010.
连结：
[7] Y. N. Jo, H. S. Kim, K. Prasanna, P. R. Ilango, W. J. Lee, S. W. Eom, et al., "Effect of Additives on Electrochemical and Corrosion Behavior of Gel Type Electrodes for Zn-Air System," Industrial & Engineering Chemistry Research, vol. 53, pp. 17370-17375, 2014.
连结：
[9] R. Shivkumar, G. P. Kalaignan, and T. Vasudevan, "Effect of additives on zinc electrodes in alkaline battery systems," Journal of power sources, vol. 55, pp. 53-62, 1995.
连结：
[10] C. W. Lee, K. Sathiyanarayanan, S. W. Eom, H. S. Kim, and M. S. Yun, "Effect of additives on the electrochemical behaviour of zinc anodes for zinc/air fuel cells," Journal of power sources, vol. 160, pp. 161-164, 2006.
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DOI可强化引用精确性、增强学术圈连结，并给予使用者跨平台的良好使用经验，目前在全世界已有超过五千万个对象申请DOI。 如想对DOI的使用与概念有进一步了解，请参考 （ ） 。

DOI可强化引用精确性、增强学术圈连结，并给予使用者跨平台的良好使用经验，目前在全世界已有超过五千万个对象申请DOI。如想对DOI的使用与概念有进一步了解，请参考（）。