题名

Structure and Elastic Properties of Iron Phosphate Glasses

作者

K. H. Chang;T. H. Lee;L. G. Hwa

关键词
期刊名称

Chinese Journal of Physics

卷期/出版年月

41卷4期(2003 / 08 / 01)

页次

414 - 421

内容语文

英文

英文摘要

The structure and elastic properties of a series of iron phosphate glasses are investigated using infrared reflectivity and ultrasonic pulse-echo measurements. The mid-infrared and far-infrared spectra give information about phosphate related vibrational modes and the nature of the bond between the metal cat-ion and its surrounding oxygen within the glass network. The structural role of the Fe2+ and Fe3+ ions in these glasses in terms of four-fold coordinated tetrahedral and/or six-fold coordinated octahedral is discussed. The room temperature ultrasonic velocities (both longitudinal and transverse) in these glasses are determined by the pulse-echo technique. The experimental results are used to obtain the elastic constants. A correlation between the structure and the elastic properties of these glasses is given.

主题分类 基礎與應用科學 > 物理
被引用次数
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