UFR-RDS試驗工場設計與操作實務

UFR-RDS Pilot Plant: Design and Operation

呂政芳(Jeng-Fan Leu)；吳豐彰(Feng-Chang Wu)；吳美燕(Meei-Yann Wu)；楊英傑(Ying-Chieh Yang)；李美津(May-Chin Lee)

上流式反應器 ； 重油加氫脫硫 ； 試驗工場 ； Up-Flow Reactor ； RDS ； Pilot Plant

石油季刊

54卷2期（2018 / 06 / 01）

31 - 42

繁體中文

台灣中油煉製研究所建置一套UFR-RDS試驗工場，用以進行UFR-RDS觸媒系統的性能評估測試。取商業RDS觸媒系統之HDM觸媒，製備成類球型UFR觸媒，裝填並串聯於RDS媒床之前。在UFR反應溫度的控制方面，導入本團隊既有的MPC（Model Predictive Control）技術，亦能夠獲得良好的效果。為了增進系統壓力的操作精準度，本工作中提出了BPR（Back Pressure Regulator）併RCV（Research Control Valve）之複合管路系統。在首次的評估測試中，全程採用本團隊的A級RDS觸媒性能測試用油－AL-VR為進料，除了以嚴苛油料驗證本試驗工場的操縱性能之外，也能以既有的A級RDS觸媒性能標準為基礎，來檢視UFR-RDS觸媒系統的表現狀況。

A pilot plant for evaluation of UFR-RDS catalyst system is built in RMRI of CPC Corp., Taiwan. Its preliminary test is conducted with a laboratory-made UFR catalyst which is modified from a commercial RDS-HDM catalyst and then loaded upstream from beds of RDS catalysts. During this pilot test, the technique of reaction temperature control by MPC (model predictive control) proposed in our previous works is succesfully applied in UFR. In order to improve accuracy of control of system pressure, an integrated system of BPR (back pressure regulator) and RCV (research control valve) is proposed. The testing feed adopt in CPC certification for A-grade RDS catalyst is applied in this preliminary run so as to confirm performance of the pilot plant and evaluate UFR-RDS catalyst on the basis of A-grade standards as well.

1. Ancheyta, J.(2011).Modeling and Simulation of Catalytic Reactors for Petroluem Refining.NJ:John Wiley & Sons.
2. Antezana, F. J.(1997).Advanced Guard Bed Technology.Chevron Residuum Hydroprocessing Symposium,San Francisco:
3. Badger Meter Europa GmbH, Valve Sizing Formulas, Valve Sizing Formulas.pdf. Retrieved from the World Wide Web: http://www.firsttech.ro/tech/pdf/VALVEtech/Badger%20Meter/Control%20Valves/Valves%20sizing%20formulas.pdf
4. Hu, D. W.,Yang, Q. H.,Dai, L. H.,Zhao, X. Q.(2013).Development and Commercial Application of Third Generation Resid Hydrotreating Catalysts.China Petroleum Processing and Petrochemical Technology,15,1-5.
5. Leu, J. F.,Wu, F. C.,Chen, S. H.(2014).Application and Tunning of Model Predictive Control: An Example of Tempeture Control for Reactors of Hydro-treating Pilot Plant.2014 Symposium on Process Systems Engineering,Sun-Mon Lake, Taiwan:
6. Spieler, S.,Mukherjee, U.,Dahlbert, A.(2006).Upgrading Residuum to Finished Products in Integrated Hydroprocessing Platforms: Solutions and Challenges.2006NPRA,Salt Lake City:
7. Takada, M.(2008).Nippon Ketjen’s Latest RDS Technologies.Hydroprocessing Catalysts Seminar for CPC,Ta-Lin, Taiwan:
8. 呂政芳,吳美燕,李美津,楊英傑,陳憲鴻,陳黝蘋,吳豐彰,林秋文,曾家瑜(2017)。105 年度研究計畫報告105 年度研究計畫報告,嘉義:台灣中油股份有限公司煉製研究所。
9. 李大東(2004).加氫處理工藝與工程.北京:中國石化出版社.