题名

聚乙烯醇對化學銅析鍍的影響及其應用在電磁波干擾遮蔽

并列篇名

Effects of Poly (vinyl alcohol) on Electroless Copper and Its Application to Electromagnetic Interference Shielding

DOI

10.29688/MHJ.201208.0002

作者

張良濤(Liang-Tau Chang);梁世明(Syh-Ming Lian);顏志超(Chih-Chao Yen)

关键词

化學鍍銅 ; 添加劑 ; 聚乙烯醇 ; 銅鍍層結晶結構 ; 添加劑銅鍍表面型態 ; 電磁波遮蔽效果 ; electroless copper plating ; additives ; polyvinyl alcohol ; surface morphology ; electromagnetic interference(EMI) shielding

期刊名称

明新學報

卷期/出版年月

38卷2期(2012 / 08 / 01)

页次

13 - 23

内容语文

繁體中文

中文摘要

本研究探討共同添加碘化鉀和聚乙烯醇對化學鍍銅鍍層之析鍍速率、表面形態、組成份、電阻之影響。結果發現添加穩定劑碘化鉀及聚乙烯醇會使析鍍速率變慢、但使鍍層的表面平整、結構緻密等。本研究另一個重點在於將析鍍後的銅箔試片運用於電磁波遮蔽方面,發現將聚乙烯醇與碘化鉀一同加入析鍍液中,會使得電磁波的遮蔽效果可達到78.7dB。

英文摘要

The main purpose of this research is to investigate the effect of potassium iodide (KI) and polyvinyl alcohol (PVA) on the plating rate, surface morphology, composition and resistivity of copper deposition. The results of adding potassium iodide and polyvinyl alcohol as additives to the borate buffered electroless copper plating solutions are that the plating rate was decreased, the surface morphology of copper deposition was smoothed and the structure of plating solution became denser. Another purpose of this study that is applying the electroless copper plating to the aspect of electromagnetic interference (EMI) shielding. It's found that by adding two additives PVA and KI together to the plating bath, EMI shielding effect (SE) is increased from 50dB to the best SE of 78.7dB.

主题分类 人文學 > 人文學綜合
基礎與應用科學 > 基礎與應用科學綜合
工程學 > 工程學綜合
社會科學 > 社會科學綜合
参考文献
  1. Ham, E. G.,Kim, E. A.,Oh, K.W.(2001).Electromagnetic interference shielding effectiveness of electroless Cu-plated PET fabrics.Synthetic Metals,123,469-476.
  2. Juskenas, R.,Jaciauskiene, J.(1998).Copper hydride formation in the electroless copper plating process: in situ X-ray diffraction evidence and electrochemical study.Electrochemica Acta,43(9),1061-1066.
  3. Lantasov, Y.,Palmans, R.,Maex, K.(2000).New plating bath for electroless copper deposition on sputtered barrier layers.Microelectronic Engineering,50,441-447.
  4. Lin, Y.M.,Yen, S.C.(2001).Efffects of additives and chelating agents on electroless copper plating.Applied Surface Science,178,116-126.
  5. Ma, Z. H.,Tan, K. L.,Kang, E. T.(2000).Electroless plating of palladium and copper on polyaniline films.Synthetic Metales,114,17-25.
  6. Mu, D.,Zhu, J.,Li, Z.,Ma, J.(2001).Electroless copper metallization on anodized aluminum metal substrates.Aluminum Finishing,12,11-13.
  7. Patterson, J. C.,Reilly, M. O.,Green, G. M.,Barrett, J.(1997).Selective electroless copper metallization on a titanium nitride barrier layer.Microelectronics Engineering,33,65-73.
  8. Shukla, S.,Seal, S.,Akesson, J.,Oder, R.,Carter, R.,Rahman, Z.(2001).Study of mechanism of electroless copper coating of fly-ash cenosphere particles.Applied Surface Science,181,35-50.
  9. Silvain, J. F.,Chazelas, J.,Trombert, S.(2000).Copper electroless deposition on NiTi shape memory ally:an XPS study of Sn-Pd-Cu growth.Applied Surface Science,153,211-217.
  10. Tarozaite, R.,Ciuksiene, N.,Butkevicius, J.(1999).Radiometric investigation of electroless copper plating from EDTA-complex, containing glycine.Journal of Radioanalytical and Nuclear Chemistry,240(1),371-374.
  11. Tzeng, S. S.,Chang, F. Y.(2001).EMI shielding effectiveness of metal-carbon fiber-reinforced ABS composites.Materials Science and Engineering,302,258-267.
  12. 吳宗蔚(2003)。碩士論文(碩士論文)。台北,國立台灣科技大學高分子工程研究所。
  13. 吳貞欽、姜智豪、王令儀、葉建宏(2002)。鎢粉無電鍍銅製程之改進研究。表面技術研討會論文集,台北:
  14. 李九龍、鄭吉良、范雲智、宋鈺、葛明德(2002)。乙醛酸無電鍍銅析鍍特性研究。表面技術研討會論文集,台北:
  15. 洪志緯(2005)。碩士論文(碩士論文)。台北,大同大學材料工程研究所。
  16. 張鈞豪(2003)。碩士論文(碩士論文)。台北,國立台灣科技大學高分子工程研究所。
  17. 陳元慶、張縈女、王振豐(2002)。利用次磷酸鹽做為還原劑的無電解銅鍍液成份及其鍍層特性之研究。表面技術研討會論文集,台北:
  18. 鄭銘章(2003)。碩士論文(碩士論文)。台北,大同大學材料工程研究所。
  19. 簡碩宏(2007)。碩士論文(碩士論文)。台北,大同大學材料工程研究所。