题名

無機聚合物製成防火材料之應用

DOI

10.6653/MoCICHE.202004_47(2).0005

作者

林凱隆;羅康維;鄭大偉;許皓翔

关键词
期刊名称

土木水利

卷期/出版年月

47卷2期(2020 / 04 / 01)

页次

21 - 25

内容语文

繁體中文

中文摘要

無機聚合物材料具有傳統卜特蘭水泥所不具備的優良性能,比如:早強、體積穩定性佳、耐化學腐蝕、界面結合能力強、抗滲性好、耐高溫性好、耐水熱作用及耐久性佳等特點。此外,從環境的角度來看,過去幾年來,廢棄物中無機聚合物材料的開發和生產越來越受到重視。許多研究顯示出在無機聚合物中使用礦渣和飛灰具有優異的機械和物理性能。無機聚合物不僅可減少卜特蘭水泥之碳足跡,且還可再利用大量的工業廢棄物,如礦渣,飛灰和矽粉。這些矽鋁酸鹽材料因富含鋁酸鹽(Al)和矽酸鹽(Si)可作為摻料。目前國內防火原料與防火建材多為進口之產品,鑒於提升國內防火材料之競爭性,使用無機聚合物可再利用大量的工業廢棄物且解決溫室氣體排放等問題,若將其發展成為新一代環保綠色材料實具有相當的潛力。本文就無機聚合物的基本理論與技術發展,針對其歷史背景、形成的條件、反應過程及防火材料相關的應用等做一整體性的回顧。

主题分类 工程學 > 土木與建築工程
工程學 > 水利工程
参考文献
  1. Bakharev, T.,Sanjayan, J.G.,Cheng, Y.B.(1999).Alkali activation of Australian slag cements.Cement and Concrete Research,29,113-120.
  2. Carreño-Gallardo, C.,Tejeda-Ochoa, A.,Perez-Ordonez, O.I.,Ledezma-Sillas, J.E.,Lardizabal-Gutierrez, D.,Prieto-Gomez, C.,Valenzuela-Grado, J. A.,Robles Hernandez, F.C.,HerreraRamirez, J.M.(2018).In the CO2 emission remediation by means of alternative geopolymers as substitutes for cements.Journal of Environmental Chemical Engineering,6,4878-4884.
  3. Davidovits, J.(1979).Synthesis of New High-Temperature GeoPolymers for Reinforced Plastics/Composites.SPE PACTFC 79,Brookfield Center, USA:
  4. Davidovits, J.(1991).Geopolymers-inorganic polymerie new materials.Journal of Thermal Analysis,37,1633-1656.
  5. Duxson, P.,Lukey, G.C.,Separovic, F.,Van Deventer, J.S.J.(2005).Effect of Alkali Cations on Aluminum Incorporation in Geopolymeric Gels.Industrial&Engineering Chemistry Research,44,832-839.
  6. Duxson, P.,Lukey, G.C.,Van Deventer, J.S.J.(2006).Thermal Conductivity of Metakaolin Geopolymers Used as a First Approximation for Determining Gel Interconnectivity.Industrial & Engineering Chemistry Research,45,7781-7788.
  7. Duxson, P.,Mallicoat, S.W.,Lukey, G.C.,Kriven, W.M.,Van Deventera, J.S.J.(2007).The effect of alkali and Si/Al ratio on the development of mechanical properties of metakaolin-based geopolymers.Colloids and Surfaces A: Physicochemical and Engineering Aspects,292,8-20.
  8. Khale, D.,Chaudhary, R.(2007).Mechanism of geopolymerization and factors influencing its development: a review.Journal of Materials Science,42,729-746.
  9. Li, C.,Sun, H.,Li, L.(2010).A review: The comparison between alkali-activated slag (Si+Ca) and metakaolin (Si+Al) cements.Cement and Concrete Research,40,1341-1349.
  10. Liang, G.W.,Zhu, H.J.,Zhang, Z.H.,Wu, Q.S.(2019).Effect of rice husk ash addition on the compressive strength and thermal stability of metakaolin based geopolymer.Construction and Building Materials,222,872-881.
  11. Pacheco-Torgal, F.,Castro-Gomes, J.,Jalali, S.(2008).Alkaliactivated binders: a review. Part 1. Historical background, terminology, reaction mechanisms and hydration products.Construction and Building Materials,22,1305-1314.
  12. Park, S.,Pour-Ghaz, M.(2018).What is the role of water in the geopolymerization of metakaolin.Construction and Building Materials,182,360-370.
  13. Provis, J.L.,Duxson, P.,Harrex, R.M.,Yong, C.Z.,Van Deventer, J.S.J.(2008).Valorisation of fly ashes by geopolymerisation.Global Nest Journal,11,147-154.
  14. Singh, N.B.,Saxena, S.K.,Kumar, M.,Rai, S.(2019).Geopolymer cement: Synthesis, Characterization, Properties and applications.Materials Today: Proceedings,15,364-370.
  15. Van Jaarsveld, J.G.S.,Van Deventer, J.S.J.,Lorenzen, L.(1999).The potential use of geopolymer materials to immobilize toxic metals: part I. Theory and applications.Minerals Engineering,10,659-669.
  16. Yip, C.K.,Lukey, G.C.,Van Deventer, J.S.J.(2005).The coexistence of geopolymeric gel and calcium silicate hydrate at the early stage of alkaline activation.Cement and Concrete Research,35,1688-1697.
  17. Zheng, G.J.,Cui, X.M.,Zhang, W.P.,Zhang, F.T.(2009).Preparation of geopolymer precursors by sol–gel method and their characterization.Journal of Materials Science,44,3991-3996.
  18. 吳冠龍(2008)。國立臺北科技大學材料及資源工程系。
  19. 枋吟霞(2008)。國立臺北科技大學材料及資源工程系。
  20. 林孟曄(2006)。國立臺北科技大學材料及資源工程系。
  21. 邱俊萍(2002)。國立臺北科技大學材料及資源工程系。
  22. 孫道勝(2005)。無機聚合物的研究與應用發展前景。材料導報,7,61-65。
  23. 陳志賢(2009)。國立成功大學土木工程學系。
  24. 蔡文傑(1996)。蔡文傑(1996),防火建材之現況與未來發展方向,工業簡訊。