| 题名 |
固態高分子電解質之研發與應用 |
| 并列篇名 |
R&D and Applications of Solid Polymer Electrolytes |
| DOI |
10.6623/chem.1995038 |
| 作者 |
鄭宗田(Tsung-Tien Cheng)；張憲彰(Hsien-Chang Chung)；溫添進(Ten-Chin Wen) |
| 关键词 |
高分子固態電解質 ； 鋰電池 ； 導電度 ； solid polymer electrolyte ； lithium battery ； conductivity |
| 期刊名称 |
化學 |
| 卷期/出版年月 |
53卷4期（1995 / 12 / 01） |
| 页次 |
359 - 368 |
| 内容语文 |
繁體中文 |
| 中文摘要 |
固態高子電解質(SPE)是一種高分子與鹽類的複合體，因具有離子導性且可製成薄膜，在電化學材料發展上受到極大的重視。本文除了對SPE的原理、種類、特性及可能用途作廣泛的介紹外，主要內容均針對鋰電池應用之相關研究進行論述。為提高SPE的導電度，並兼顧適當的機械強度起見，許多研究致力於高分子基材的設計改良。本文依設計原理不同，大致區分為：單一高分子改質、複合式高分子電解質、單離子傳導體、膠質電解質四類分別闡述說明。性能評估方面，如導電度、陽離子轉移係數、電化學穩定性、極化阻抗等主要性質，藉交流阻抗分析、循環伏安法、線性伏安法等分析之結果整理報告之。 |
| 英文摘要 |
Solid polymer electrolyte (SPE) is a complex material consisting of polymer and salts. It is attracted by employing SPE in electrochemical material development because of its ionic conductivity and feasibility to creat thin film. In this review, we focused mainly on the studies of application about lithium battery as well as many others. In order to improve conductivity and keep certain strength, extensive studies have focused on new designs of the polymer substrate. By different approaches, these new SPEs are classified into four categories: modified homopolymer host, composite polymer electrolyte, single-ion conductor, and gel electrolyte. The properties of conductivity, cation transference number, electrochemical stability, and polarization resistance were used to evaluate the polymer electrolytes. The electrochemical methods, such as AC impedance analysis, cyclic voltammetry, and linear sweep voltammetry, employed in measuring the above properties are introduced respectively. |
| 主题分类 |
基礎與應用科學 >
化學 |
| 被引用次数 |
