多孔性金屬－有機配位聚合物的建構及其儲氫性質研究

Fabrication of Metal-Organic Frameworks for Hydrogen Storage

10.6623/chem.2008010

羅左財(Tzuoo-Tsair Luo)；呂光烈(Kuang-Lieh Lu)

氫氣儲存 ； 配位聚合物 ； 能源利用 ； 孔洞材料 ； Hydrogen storage ； Metal-organic frameworks ； Energy utility ； Porous materials

化學

66卷2期（2008 / 06 / 01）

109 - 116

繁體中文

以簡單、有效、成本低廉的自組裝反應所合成的多孔性金屬–有機配位聚合物具有很好的氫氣儲存潛力，為目前重要而熱門的研究課題。本文探討多孔性金屬−有機配位聚合物的建構原理，用以認識其立體孔洞結構；其次分析影響氫氣儲存效率的因素，列舉較前端發展的儲氫實例，並提出未來的展望。

Porous metal–organic frameworks (MOFs) with designable and tunable intrinsic properties represent a remarkable advance in materials science, especially for applications in gas storage and separation. Thanks to effective design strategy, highly porous frameworks can be efficiently prepared. Hydrogen storage is a timely and hot research topic, owing to gradual shortage of fossil fuels and the increasing green-house effect. This review focuses on the fabrication of MOFs and their structural concept that is useful for hydrogen storage. Finally, recently reported porous MOFs that possess remarkable hydrogen storage efficiency are highlighted.