| 题名 |
節能性金屬有機骨架試量產製程開發及其節能應用 |
| 并列篇名 |
Development of Metal-Organic Frameworks Production and its application in energy conservation |
| DOI |
10.29911/JEHVACE_NEW.202301_(137).0006 |
| 作者 |
周揚震(Yiang-Chen Chou)；黃德一(De-Yi Huang)；謝宗霖(Tsung-Lin Hsieh)；盧勁宏(Jing-Hung Lu)；陳鈞振(Jiun-Jen Chen)；康育豪(Yu-Hao Kang) |
| 关键词 |
金屬有機骨架 ； 試量產製程 ； 壓縮空氣乾燥 ； 節能效益 ； Metal-Organic Frameworks ； Pilot-scale production process ； Compressed air drying ； Energy conservation |
| 期刊名称 |
冷凍空調&能源科技 |
| 卷期/出版年月 |
137期（2023 / 01 / 10） |
| 页次 |
60 - 65 |
| 内容语文 |
英文 |
| 中文摘要 |
本研究開發國內首座低耗能金屬有機骨架（Metal-Organic Frameworks，MOFs）吸附劑試量產製程，量產節能型吸附劑，於實際場域進行壓縮空氣乾燥效能驗證。研究中以水熱反應質能平衡、反應單元放大以及造粒製程危害等分析結果，進行整體製程規劃。分析結果顯示：MOF合成不受藥品等級、進料模式及反應溫度（60～95°C）影響，轉化率可達98.8%。該試量產製程每批次可量產71公斤MOF粉體，用於量產2～5mm MOF顆粒，其吸水率等同小量合成MOF。MOF吸附式乾燥機於實際場域測試，可將相對濕度近100%、表壓7kg/cm^2之壓縮空氣乾燥至-30°C露點溫度以下，同時達到2%節能量。未來應釐清系統最佳操作參數，進一步提昇製程節能效益。 |
| 英文摘要 |
The aim of this study is to design a pilot-scale Metal-Organic Frameworks (MOFs) production process for manufacturing 2~5 mm MOF pellets by assessing the mass balance in hydrothermal reaction, reactor selection, and granulation process risk. The produced MOF pellets were used to dry the compressed air in a real industrial process. The dehumidification and energy conservation performance of the MOF installed compressed air dryer was examined subsequently. Experimental results indicated that the chemical grade, reactant feeding process, and reaction temperature in the range of 60 to 95°C did not alter the conversation of MOF synthesis. 71 kg MOF was produced in batch reaction. The granulated MOF in 2~5mm diameter showed tiny water adsorption decay as compared to the MOF synthesized from lab-scale reaction. The dew point below -30°C and 2% energy promotion were achieved for the dryer for experiments conducted in 100%RH and 7 kg/cm^2 compressed air. The operating condition of the dryer has to be optimized in further works, that is benefit to promote the progress of MOF application in a commercial industrial process. |
| 主题分类 |
工程學 >
電機工程 |
| 参考文献 |
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