以螢光光譜探討金屬有機骨架之結構

Fluorescence Probing of Metal-Organic Frameworks Structures

10.6840/cycu201700104

郭彥豐

螢光 ； 金屬有機骨架 ； 染料 ； 猝滅 ； metal-organic frameworks ； fluorescence ； quenching ； dye

中原大學化學系學位論文

2017年

碩士

李世琛

繁體中文

本研究利用螢光光譜觀察史托克斯位移探討不同極性的有機溶劑對於鋁系列金屬有機骨架之作用力。我們測量有機溶劑造成金屬有機骨架的能隙變化，以及不同電性的染料(甲基橙與亞甲基藍)對於不同孔徑大小金屬有機骨架造成的吸附行為。金屬有機骨架為一種孔洞型材料，會因為溶劑效應而產生不同的作用力。因此我們利用螢光光譜測量，觀察鋁系列金屬有機骨架吸附不同極性有機溶劑的史托克斯位移，再比較不同孔徑大小的鋁系列金屬有機骨架，進而探討其吸附行為。我們也測量鋁系列金屬有機骨架吸附不同極性有機溶劑的能隙，探討其吸附行為是否在金屬有機骨架的孔洞內或是孔洞外之差別。最後我們利用Langmuir吸附公式計算鋁系列金屬有機骨架吸附甲基橙與亞甲基藍的靜態吸附常數KS；我們也利用非線性Stern-Volmer plot計算鋁系列金屬有機骨架吸附甲基橙與亞甲基藍的動態猝滅常數KD，進而探討不同電性的染料對於不同孔徑大小金屬有機骨架造成的吸附行為。

In this study, intermolecular force of the aluminum-based metal-organic frameworks caused by organic solvents with different polarities were explored using fluorescence spectroscopy to observe Stokes shift. Band gap changes of metal-organic frameworks caused by organic solvents were measured, and the adsorption behaviors of dyes with different electric properties (methyl orange and methylene blue) on metal-organic frameworks with different pore sizes were studied. Metal-organic framework is a porous material that may present different structural intermolecular force due to solvent effects. Therefore, by adopting fluorescence spectroscopy for measurement, the Stokes shifts shown by aluminum-based metal-organic frameworks adsorbing organic solvents with different polarities were observed; moreover, the adsorption behaviors of aluminum-based metal-organic frameworks with different pore sizes were compared. The band gaps of aluminum-based metal-organic frameworks adsorbing organic solvents with different polarities were also measured, and whether the adsorption took place inside or outside the pores of metal-organic frameworks was examined. Finally, Langmuir adsorption isotherm was used to calculate the static adsorption constants (KS) of aluminum-based metal-organic frameworks adsorbing methyl orange and methylene blue; meanwhile, non-linear Stern-Volmer plot was adopted to calculate the dynamic quenching constants (KD) of aluminum-based metal-organic frameworks adsorbing methyl orange and methylene blue, so as to explore the adsorption behaviors of metal-organic frameworks with different pore sizes with dyes having different polarities.

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