题名

氯鹽對Fenton程序去除染料的影響

并列篇名

Effect of Chloride Ion on the Dye Degradation of Fenton Process

DOI

10.6665/JLYIT.2013.12.1

作者

游非庸(Fei-Yung Yu)

关键词

Fenton程序 ; 染料廢水 ; 氯鹽 ; Fenton process ; dye wastewater ; chloride ion

期刊名称

蘭陽學報

卷期/出版年月

12期(2013 / 06 / 01)

页次

1 - 8

内容语文

繁體中文

中文摘要

本研究使用RB19染料廢水,以Fenton程序進行染料去除反應,在不同鐵鹽作用下,加入氯離子比較其去除效果,實驗以250 ml錐形瓶,在恆溫振盪器為之,溫度維持在30℃,轉速設定在160rpm,過氧化氫、鐵鹽、氯鹽及氧化時間為操作變數。實驗結果顯示,Fenton氧化程序去除染料效果良好,且在相同加藥量下,硫酸亞鐵去除染料效果優於硫酸亞鐵銨;比較氯鹽的影響,對於硫酸亞鐵銨負影響大於硫酸亞鐵。

英文摘要

The water sample synthetic RB19 was investigated for the removal of dye as function of ferric-salt and chloride ion during Fenton degradation in this study. The experiments were conducted in 250-ml flasks, which were capped and shaken in a isothermal oscillator tank with oscillation speed set at 160 rpm. The dosages of H2O2, ferric-salt, chloride ion and oxidation time are the operate parameters. These results show degradation in the Fenton process are feasible. The efficiency was in the order FeSO4.7H2O> FeSO4(NH4)2 SO4.6H2O. The FeSO4(NH4)2 SO4.6H2O has larger negative effect for chloride ion dosage.

主题分类 人文學 > 人文學綜合
基礎與應用科學 > 基礎與應用科學綜合
醫藥衛生 > 醫藥衛生綜合
生物農學 > 生物農學綜合
工程學 > 工程學綜合
社會科學 > 社會科學綜合
社會科學 > 社會學
参考文献
  1. 游非庸、黃惠蓉(2011)。硫酸對 Fenton 程序去除染料的影響。蘭陽學報,10,6。
    連結:
  2. Arslan, I.,Balcioglu, I.A.,Tuhkanen, T.,Bahnemann, D(2000).H2O2/UV-C and Fe2+/H2O2/UV-C Versus TiO2/UV-A Treatment for Reactive Dye Wastewater.Journal of Environmental Engineering,126(10),903-911.
  3. Bali, U.,Karagözoğlu , B.(2007).Performance comparison of Fenton process, ferric coagulation and H2O2/pyridine/Cu(II) system for decolorization of Remazol Turquoise Blue G-133.Dyes and Pigments,74,73-80.
  4. De Laat, J.,Le, G. T.,Legube, B.(2004).A Comparative Study of the Effects of Chloride, Sulfate and Nitrate Ions on the Rates of Decomposition of H2O2 and Organic Compounds by Fe(II)/H2O2 and Fe(III)/H2O2.Chemosphere,55,715-723.
  5. Kang, S. F.,Hsu, S. C.,Chang, H. M.(1997).Coagulation of Textile Secondary Effluents with Fenton's Reagent.Wat. Sci. Technol.,36,215-222.
  6. Kim, T. H.,Park, C.,Yang, J.,Kim, S.(2004).Compare of Disperse and Reactive Dye Removals by Chemical Coagulation and Fenton Oxidation.J. Hazard. Mater.,112(1-2),95-103.
  7. Lin, S. H.,Lai, C. L.(2000).Kinetic Characteristics of Textile Wastewater Ozonation in Fluidized and Fixed Activated Carbon Beds.Wat. Res.,34,763-772.
  8. Lu, M. C.,Chen, J. N.,Chang, C. P.(1997).Effect of Inorganic Ions on the Oxidation of Dichlorvos Insecticide with Fenton's Reagent.Chemosphere,35,2285-2293.
  9. Maezono, T.,Tokumura, M.,Sekine, M.,Kawase, Y.(2011).Hydroxyl radical concentration profile in photo-Fenton oxidation process: Generation and consumption of hydroxyl radicals during the discoloration of azo-dye Orange II.Chemosphere,82,1422-1430.
  10. Perez, M.,Torrades, F.,Domenech, X.,Peral, J.(2002).Fenton and Photo-Fenton Oxidation of Textile Effluents.Wat Res,36,2703-2710.
  11. Rosenfeldt, E. J.,Linden, K. G.,Canonica, S.,Gunten, U. V.(2006).Comparison of the Efficiency of OH. Radical Formation During Ozonation and the Advanced Oxidation Processes O3/H2O2 and UV/H2O2.Water Res.,40,3695-3704.
  12. 游非庸、康世芳、廖志祥(2002)。Fenton 程序分解染料及脫色動力學。第 27 屆廢水研討會