鋅/鎵(亞)磷酸鹽的合成、結構與性質研究

謝明哲

山西大学，您好！

感谢采购，人社期刊库｜人社论文库，期间：2025/01/01~2025/12/31

感谢试用，科学期刊库｜科学论文库，期间：2024/10/20~2025/01/20

浏览高级检索

关闭
检索检索高级检索出版物检索
浏览期刊主题浏览核心期刊浏览期刊拼音浏览

关闭

查询符号(半角)	查询符号意义说明
空格	表示为「AND」两个查询词之交集
双引号 ( " " )	片语以双引号标示开始及结束，而且只寻找出现顺序相同的字词，例： " image process "
?	表示一个字母切截，输入两个?表两个字母，依此类推，例：输入「Appl?」，查得结果应为appl e , appl y … ( 常用于英文字查询 )
*	表示不限字母切截，由0~n. 例：输入「appl*」，查得结果应为appl e , appl es , appl y , appl ied , appl ication … ( 常用于英文字查询 )
AND、OR、NOT	布尔逻辑组合关键字，用来扩大或缩小查询范围的技巧。 (1) AND ：缩小查询范围 (2) OR ：扩大查询范围(3) NOT：排除不相关的范围

DOI 是数位物件识别码（ D igital O bject I dentifier ）的简称，
为物件在网路上的唯一识别码，可用于永久连结并引用目标物件。

使用DOI作为永久连结

每个DOI号前面加上「 http://dx.doi.org/ 」便成为永久网址。
如以DOI号为 10.5297/ser.1201.002 的文献为例，此文献的永久连结便是： http://dx.doi.org/ 10.5297/ser.1201.002 。
日后不论出版单位如何更动此文献位置，永久连结所指向的位置皆会即时更新，不再错失重要的研究。

引用含有DOI的文献

有DOI的文献在引用时皆应同时引用DOI。若使用APA、Chicago以外未规范DOI的引用格式，可引用DOI永久连结。

DOI可强化引用精确性、增强学术圈连结，并给予使用者跨平台的良好使用经验，目前在全世界已有超过五千万个对象申请DOI。如想对DOI的使用与概念有进一步了解，请参考（）。

书目管理工具

相关连结

问题回报

全文下载

锌/镓(亚)磷酸盐的合成、结构与性质研究

Syntheses, Structures and Properties of Zinc / Gallium Phosphates / Phosphites

谢明哲 , 博士　　导师：王素兰　　

繁体中文

二氧化碳吸附；微孔材料；金属磷酸盐；金属亚磷酸盐； carbon dioxide adsorption ； microporous materials ； metal phosphates ； metal phosphites

0 个人觉得这篇文章赞

摘要 │ 参考文献 (19) │ 国际计量

摘要〈TOP〉

并列摘要〈TOP〉

The synthesis, structural characterization, and properties of seven compounds are included in this thesis. Among them, four are gallium phosphites, one is gallium zincophosphite, and two are organic-inorganic hybrid zinc phosphates. The crystal structures and chemical formulas for all compounds were determined by single-crystal X-ray diffraction analysis; the purity was examined by comparing powder diffraction patterns with theoretical patterns; gas sorption and optical properties were also measured. Based on different metal centers, correlations of structure, these compounds are grouped into three systems for discussion, namely system A, B, and C.
　　System A, the “template-cladded” strategy was proposed: the free space of the channels would be created if the organic template were pushed toward the inorganic channel wall. Herein, we chose long-alkyl-chain polyamines as the template and successfully synthesized A1 and NTHU-15 series compound in different ratios of solvents. The structural features of A1 and NTHU-15 are different, long-alkyl-chain polyamine templates blocked the channel space in Al but not in NTHU-15. The organic templates anchor onto the inorganic channel walls, and therefore succeeded in releasing channel space of up to ~24 % of solvent accessible volume. NTHU-15 displays significant carbon dioxide selective adsorption, and has been successful at overcoming the long-standing problem of organic-templated extra-large-channel structures as opposed to a "true open" framework.  
　　System B, the development of NTHU-13 series were continued, using the long-alkyl-chain monoamines (tetradecylamine, 14C) as templates to synthesize extra-large channel gallium zincophosphite (56R-NTHU-13), and enlarge the channel size from 48R microporous to 56R mesoporous. Besides, previously reported microporous structures have been synthesized by template-directed hydrothermal or solvothermal synthesis; however, the structural channels have not been controlled by using any specific type of template molecule. By using long-alkyl-chain monoamines, the systematic synthetic method and the channel size and the structural connectivity can be achieved and predicted in NTHU-13 series, and the success of the system is a major breakthrough.
　　System C, we continued the research of NTHU-11 and (H2tmdp)[Zn2(HPO4)2(m-bdc)] (D), which were various optical analogues with identical structures. Two optical analogues of NTHU-2, namely C-120 and C-160 were prepared by a minute amount of solvent under 120 oC and 160 oC, respectively. Their optical properties can be changed with increasing temperature. C-160 and D-160 display yellow-orange light with peaks centered at 600 nm. Further measurements showed that the unusual photoluminescence properties are caused by free radical, which were formed from tmdp by higher temperature and examined by EPR experiment.

参考文献 ( 19 ) 〈TOP〉

[1]　(a) D. W. Breck, Zeolite Molecular Sieves,Wiley, New York, 1974; (b) J. M. Thomas, R. Raja, G. Sankar, R. G. Bell, Nature 1999, 398, 227; (c) R. D. Miller, Science 1999, 286, 421; (d) J. M. Thomas, Angew. Chem., Int. Ed. 1999, 38, 3588; (e) S. M. Kuznickl, et al. Nature 2001, 412, 720 ; (f) M. E. Davis, Nature 2002, 417, 813; (g) M. Eddaoudi, J. Kim, N. Rosi, D. Vodak, J.Wachter, M. O’Keeffe, O. M. Yaghi, Science 2002, 295, 469; (h) P. M. Forster, J. Eckert, J. S. Chang, S. E. Park, G. Férey, A. K. Cheetham, J. Am. Chem. Soc. 2003, 125, 1309; (i) S. Kitagawa, R. Kitaura, S. Noro, Angew. Chem. Int. Ed. 2004, 43, 2334; (j) R. Murugavel, A. ChoudHury, M. G. Walawalkar, R. Pothiraja, C. N. R. Rao, Chem. Rev. 2008, 108, 3549.
连结：
[3]　R. M. Barrer, J. Chem. Soc. 1948, 127.
连结：
[7]　H. Li, M. Eddaoudi, M. O'Keeffe, O. M. Yaghi, Nature 1999, 402, 276.
连结：
[8]　A. P. Cote, A. I. Benin, N. W. Ockwig, M. O’Keeffe, A. J. Matzger, O. M. Yaghi, Science 2005, 310, 1166
连结：
[12]　D. Maspoch, D. Ruiz-Molina, J. Veciana, Chem. Soc. Rev. 2007, 36, 770.
连结：

国际计量

〈TOP〉

E-mail ：

文章公开取用时，将寄通知信至您填写的信箱地址

E-mail ：

使用DOI作为永久连结

引用含有DOI的文献

DOI可强化引用精确性、增强学术圈连结，并给予使用者跨平台的良好使用经验，目前在全世界已有超过五千万个对象申请DOI。 如想对DOI的使用与概念有进一步了解，请参考 （ ） 。

DOI可强化引用精确性、增强学术圈连结，并给予使用者跨平台的良好使用经验，目前在全世界已有超过五千万个对象申请DOI。如想对DOI的使用与概念有进一步了解，请参考（）。