以二氧化錫薄膜為基底之多重離子感測器之研製及應用

鄭瑞福

doi:10.6840/cycu201100532

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以二氧化锡薄膜为基底之多重离子感测器之研制及应用

Fabrication and Applications of the Multi-ions Sensors Based on SnO2 Thin Film

郑瑞福 , 博士　　导师：　　

英文 DOI： 10.6840/cycu201100532

二氧化锡/氧化铟锡玻璃；酸硷感测器；钾离子感测器；钠离子感测器；氯离子感测器；无线居家照护系统；多重离子感测系统；非理想效应校正方法； pH sensor ； Potassium sensor ； Tin oxide (SnO2)/ indium tin oxide (ITO) glass ； Sodium sensor ； Chloride sensor ； Non-ideal effects calibration method ； Multi-ions sensing system ； Wireless home-care system.

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摘要 │ 参考文献 (150) │ 国际计量

摘要〈TOP〉

在本论文中，系以二氧化锡(Tin oxide, SnO2)/氧化铟锡(Indium tin oxide glass, ITO glass)玻璃为基材进行钾、钠与氯三种全固态离子感测器之研制。三种离子感测器之感测膜系分别由相对之聚氯乙烯(Polyvinylchloride, PVC)、塑化剂(Dis (2-ethylhexyl) sebacate, DOS)、离子选择物(Ionophores)与离子添加物(Additives)混合而成。 经过最佳化实验之後，钾离子感测器之最佳重量比是PVC: DOS: Valinomycin: KTpClPB = 33:66:4:2、钠离子感测器之最佳重量比是PVC: DOS: B12C4: NaTFBD = 33:66:2:5与氯离子感测器之最佳重量比是PVC: DOS: ETH9033: TDDMACl = 33:66:2:5。在此最佳化条件下，三种感测器之感测度、线性区间、最低侦测极限、反应时间与寿命时间分别被量测出来。此外，三种感测器的选择系数系以电压匹配法(Matched potential method, MPM)为模式也被量测出来。另外，钠离子感测器与氯离子感测器也被应用於量测眼镜冲洗缓冲液(Rinsing solution for contact lenses)上。 在本论文中，亦发展结合硬体与软体方式之非理想效应校正方法，此非理想效应校正方法亦应用於全固态钾离子感测器上。非理想效应之时漂和迟滞的测量条件被设定为：时漂持续时间为12个小时，迟滞回圈为10-3M→10-1M→10-3M→10-5M→10-3M氯化钾(KCl)溶液浓度，迟滞回圈之总量测时间为5分钟。时漂校正浓度为10-2M和10-5M氯化钾溶液浓度。另外，交流阻抗分析仪(Alternated current impedance analyzer)也被使用於测量感测膜的交换阻抗。交流阻抗分析仪之量测结果被用於解释感测膜之迟滞和感测膜的交换阻抗之间关系。 最後，本论文亦发展包括酸硷、钾、钠和氯之多重离子感测器并结合无线居家照护系统。多重离子感测器在不同测试溶液下之交连(Correlation)系数亦被探讨。本论文亦探讨无线居家照护系统之感测器模组、可携式模组、蓝芽(Bluetooth)模组、个人电脑(Personal computer, PC)的终端与可携式单元。测量结果之数据记录和被显示系使用Lab-VIEW软件所设计的图形化界面。结果，此无线居家照护系统可即时且顺利地监测和传送量测信号。

并列摘要〈TOP〉

In this thesis, three all-solid-state sensors include potassium, sodium, and chloride based on tin oxide (SnO2)/ indium tin oxide (ITO) glass were developed. The sensing membranes of three sensors were prepared by mixing poly (vinyl chloride) (PVC), bis (2-ethylhexyl) sebacate (DOS), ionophores, and additives. 
After the optimum experimental trials, the best weight ratio of the potassium sensor was PVC: DOS: Valinomycin: KTpClPB = 33:66:4:2. The sodium sensor was PVC: DOS: B12C4: NaTFBD = 33:66:2:5. And, the chloride sensor was PVC: DOS: ETH9033: TDDMACl = 33:66:2:5. In the optimum condition, the sensitivity, linear concentrations, low detection limit, response time, and lifetime of the sensors were measured. Moreover, the selectivity coefficients by matched potential method (MPM) of the sensors were tested. In addition, sodium and chloride sensors were applied to detect rinsing solution for contact lenses. 
In this thesis, a non-ideal effects calibration method combining of hardware and software was developed, and apply this calibration method to an all-solid-state potassium electrode. The measurement conditions of drift and hysteresis were set as below; the drift time was last for 12 hours, the hysteresis loop was 10-3M→10-1M→10-3M→10-5M→10-3M KCl solutions, and the total loop time of hysteresis measurement was 5 min. Calibration of drift behaviors were in 10-2M and 10-5M KCl solutions. In addition, the alternated current (AC) impedance analyzer was used to measure the transfer impedance of the sensing membrane. The experimental results obtained by the AC impedance analyzer were used to explain the relationship between the hysteresis and transfer impedance of the sensing membrane.
Finally, this thesis developed a multi-ions sensing system includes pH, potassium, sodium, and chloride ion sensors with a wireless home-care system. The correlations of the sensors in multi-ions sensing system under different test solutions were discussed. This thesis also investigated sensors module, portable module, Bluetooth module, personal computer (PC) terminal, and portable unit of the wireless home-care system. A graphical measurement interface for data recorded and measurement results displayed was designed by Lab-VIEW software. Therefore, the wireless home-care system could successfully monitor and transmit the sensing signals in real time.

参考文献 ( 150 ) 〈TOP〉

[1] Yoshio Umezawa, Philippe Buhlmann, Kayoko Umezawa, Koji Tohda, and Shigeru Ameriya, “Potentiomseric selectivity coefficients of ion-selective electrodes part I. inorganic cations”, Pure Appl. Chem., Vol. 72, No. 10, pp. 1851–2082, 2000.
连结：
[2] A. Errachid, J. Bausells, N. Zine, H. Jaffrezic, C. Martelet, N. Jaffrezic-Renault, and M. Charbonnier, ”Analytical features of K+-sensitive membrane obtained by implantation in silicon dioxide films”, Materials Science and Engineering, Vol. C 21, pp.9-13, 2002.
连结：
[3] Eugenia Totu, Ana Maria Josceanu, and Arthur K. Covington, “Improved potassium-selective membrane using valinomycin as ionophore for ion-selective microdevices”, Materials Science and Engineering C, Vol. 18, pp.87–91, 2001.
连结：
[4] Lee Yook Heng and Elizabeth A.H. Hall, ”Assessing a photocured self-plasticised acrylic membrane recipe for Na+ and K+ ion selective electrodes”, Analytica Chimica Acta, 443, pp.25-40, 2001.
连结：
[5] T. Momma, S. Komaba, M. Yamamoto, T. Osaka, and S. Yamauchi, ”All-solid-state potassium-selective electrode using double-layer film of polypyrrole polyanion composite and plasticized poly(vinyl chloride) containing valinomycin”, Sensors and Actuators, B 24-25, pp.724-728, 1995.
连结：

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