具多重結構之仿生聚苯胺在超級電容之應用

林振為

doi:10.6840/cycu201600852

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具多重结构之仿生聚苯胺在超级电容之应用

Bio-inspired polyaniline with multi-structure for supercapacitor application

林振为 , 硕士　　导师：李有璋　　

繁体中文 DOI： 10.6840/cycu201600852

多层次结构；聚苯胺；超级电容； hierarchy structure ； polyaniline ； supercapacitor

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摘要 │ 参考文献 (27) │ 国际计量

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This paper proposes a method for the creation of molds with hierarchical micro/nano structures to enable the imprinting of conductive polymer polyaniline (PANI) for use as an electrode. The mold used for micro/nano structures was produced artificially. Photolithography was used to define an array of circular structures on a silicon substrate, followed by dry etching to create an array of cylinders with a diameter and height of 5 μm. Then nano pattern was produced and performed by dry etching to create a hierarchical structure. PDMS was used to form a soft mold to transfer this hierarchical structure to a PANI film, apply in the supercapacitor. 
　　Using field emission scanning electron microscope (FE-SEM) confirmed that the surface structure of the film identification. On a three-electrode electrochemical cell, experiments were performed to characterize the electrochemical properties of plane PANI and PANI with microstructure and hierarchical microstructure, respectively. Cyclic voltammetric (CV), galvanostatic charge–discharge, and electrochemical impedance spectroscopy (EIS) measurements were then conducted using 1M H2SO4 as an electrolytic solution. 
　　Its specific capacity value was obtained by the electrochemical measurement. Experiment results demonstrate that its specific capacity was 530 F/g, which is higher approximately 96% compared with PANI plane film , . Our results show that increasing the surface area of PANI through the inclusion of hierarchical structures enhanced oxidation/reduction reactions, leading to a higher average specific capacitance.

参考文献 ( 27 ) 〈TOP〉

[1] A. Burke, 2000, “Ultracapacitors: why, how, and where is the technology”, J. Power Sources, Vol. 91, pp. 37-50.
连结：
[2] R. Kötz, and M. Carlen, 2000, “Principles and applications of electrochemical capacitors”, Electrochim. Acta, Vol. 45, pp. 2483-2498.
连结：
[3] G. Wang, L. Zhang, and J, Zhang, 2012, “A review of electrode materials for electrochemical supercapacitors”, Chem. Soc. Rev, Vol. 41, pp. 797-828.
连结：
[4] B. E. Conway, V. Birss, and J. Wojtowicz, 1997, “The role and utilization of pseudocapacitance for energy storage by supercapacitors”, J. Power Sources, Vol. 66, pp. 1-14.
连结：
[5] Y. Zhang, H. Feng, X. Wu, L. Wang, A. Zhang, T. Xia, H. Dong, X. Li, and L. Zhang, 2009, “Progress of electrochemical capacitor electrode materials: A review”,Int. J. Hydrogen Energy, Vol. 34, pp.4889-4899.
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DOI可强化引用精确性、增强学术圈连结，并给予使用者跨平台的良好使用经验，目前在全世界已有超过五千万个对象申请DOI。如想对DOI的使用与概念有进一步了解，请参考（）。